Discussion Addendum for: Indium‐Catalyzed Heteroaryl–Heteroaryl Bond Formation through Nucleophilic Aromatic Substitution: Preparation of 2‐Methyl-3-(thien-2‐yl)‐1H-indole

Teruhisa Tsuchimoto

Organic Syntheses   100   287 - 303   2023

Stepwise Suzuki−Miyaura Cross‐Coupling of Triborylalkenes Derived from Alkynyl−B(dan)s: Regioselective and Flexible Synthesis of Tetrasubstituted Alkenes Invited Reviewed

Tomohiro Tani, Naomi Takahashi, Yuuki Sawatsugawa, Mana Osano, Teruhisa Tsuchimoto

Advanced Synthesis & Catalysis   363 ( 9 )   2427 - 2442   2021.4

In(ONf)3-catalyzed 7-membered carbon-ring-forming annulation of heteroarylindoles with α,β-unsaturated carbonyl compounds Reviewed

Teruhisa Tsuchimoto, Takahiro Johshita, Kazuhiro Sambai, Naoki Saegusa, Takumi Hayashi, Tomohiro Tani, Mana Osano

Organic Chemistry Frontiers   8 ( 12 )   2882 - 2892   2021

Front cover: In(ONf)3-catalyzed 7-membered carbon-ring-forming annulation of heteroarylin- doles with α,β-unsaturated carbonyl compounds

Teruhisa Tsuchimoto, Takahiro Johshita Kazuhiro Sambai, Naoki Saegusa, Takumi Hayashi, Tomohiro Tani and Mana Osano

Organic Chemistry Frontiers   8 ( 12 )   2867 - 2867   2021

Front Cover Picture: Zinc/Indium Bimetallic Lewis Acid Relay Catalysis for Dehydrogenative Silylation/Hydrosilylation Reaction of Terminal Alkynes with Bis(hydrosilane)s (Adv. Synth. Catal. 19/2020)

Tomohiro Tani, Yudai Sohma, Teruhisa Tsuchimoto

Advanced Synthesis & Catalysis   362 ( 19 )   3925 - 3925   2020.10

Zinc/Indium Bimetallic Lewis Acid Relay Catalysis for Dehydrogenative Silylation/Hydrosilylation Reaction of Terminal Alkynes with Bis(hydrosilane)s Reviewed

Tomohiro Tani, Yudai Sohma, Teruhisa Tsuchimoto

Advanced Synthesis & Catalysis   362 ( 19 )   4098 - 4108   2020.10

Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons Reviewed

Hiroto Yoshida, Michinari Seki, Shintaro Kamio, Hideya Tanaka, Yuki Izumi, Jialun Li, Itaru Osaka, Manabu Abe, Hiroki Andoh, Tomoki Yajima, Tomohiro Tani, Teruhisa Tsuchimoto

ACS Catalysis   10 ( 1 )   346 - 351   2020.1

A Drastic Effect of TEMPO in Zinc‐Catalyzed Stannylation of Terminal Alkynes with Hydrostannanes via Dehydrogenation and Oxidative Dehydrogenation Reviewed

Yuichi Kai, Shinya Oku, Tomohiro Tani, Kyoko Sakurai, Teruhisa Tsuchimoto

Advanced Synthesis & Catalysis   361 ( 18 )   4314 - 4323   2019.9

Cover Picture: Alkylation of Terminal Alkynes under Zinc Lewis Acid Catalysis and Its Mechanistic Studies (Adv. Synth. Catal. 12/2019)

Mana Osano, Takeru Kida, Kyohei Yonekura, Teruhisa Tsuchimoto

Advanced Synthesis & Catalysis   361 ( 12 )   2736 - 2736   2019.6

Alkylation of Terminal Alkynes under Zinc Lewis Acid Catalysis and Its Mechanistic Studies Reviewed

Mana Osano, Takeru Kida, Kyohei Yonekura, Teruhisa Tsuchimoto

Advanced Synthesis & Catalysis   361 ( 12 )   2825 - 2831   2019.6

Front Cover Picture: Alkynyl−B(dan)s in Various Palladium‐Catalyzed Carbon−Carbon Bond‐Forming Reactions Leading to Internal Alkynes, 1,4‐Enynes, Ynones, and Multiply Substituted Alkenes (Adv. Synth. Catal. 8/2019)

Tomohiro Tani, Yuuki Sawatsugawa, Yusuke Sano, Yo Hirataka, Naomi Takahashi, Sadahiro Hashimoto, Tetsuya Sugiura, Teruhisa Tsuchimoto

Advanced Synthesis & Catalysis   361 ( 8 )   1699 - 1699   2019.4

Alkynyl−B(dan)s in Various Palladium‐Catalyzed Carbon−Carbon Bond‐Forming Reactions Leading to Internal Alkynes, 1,4‐Enynes, Ynones, and Multiply Substituted Alkenes Reviewed

Tomohiro Tani, Yuuki Sawatsugawa, Yusuke Sano, Yo Hirataka, Naomi Takahashi, Sadahiro Hashimoto, Tetsuya Sugiura, Teruhisa Tsuchimoto

Advanced Synthesis & Catalysis   361 ( 8 )   1815 - 1834   2019.4

A Heteroarylamine Library: Indium-Catalyzed Nucleophilic Aromatic Substitution of Alkoxyheteroarenes with Amines Reviewed

Kyohei Yonekura, Yasuhiro Yoshimura, Mizuri Akehi, Teruhisa Tsuchimoto

Advanced Synthesis and Catalysis   360 ( 6 )   1159 - 1181   2018.3

Indium-Catalyzed Annulation of o-Acylanilines with Alkoxyheteroarenes: Synthesis of Heteroaryl[b]quinolines and Subsequent Transformation to Cryptolepine Derivatives Invited Reviewed

Kyohei Yonekura, Mika Shinoda, Yuko Yonekura, Teruhisa Tsuchimoto

Molecules   23 ( 4 )   838;1 - 18   2018

Zinc-Catalyzed Dehydrogenative Silylation of Indoles Reviewed

Kyohei Yonekura, Yoshihiko Iketani, Masaru Sekine, Tomohiro Tani, Fumiya Matsui, Daiki Kamakura, Teruhisa Tsuchimoto

ORGANOMETALLICS   36 ( 17 )   3234 - 3249   2017.9

Indium-Catalyzed Regioselective beta-Alkylation of Pyrroles with Carbonyl Compounds and Hydrosilanes and Its Application to Construction of a Quaternary Carbon Center with a beta-Pyrrolyl Group Reviewed

Shota Nomiyama, Takahiro Ogura, Hiroaki Ishida, Kazuki Aoki, Teruhisa Tsuchimoto

JOURNAL OF ORGANIC CHEMISTRY   82 ( 10 )   5178 - 5197   2017.5

Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition Reviewed

Yoshihiro Sohtome, Genta Nakamura, Atsuya Muranaka, Daisuke Hashizume, Sylvain Lectard, Teruhisa Tsuchimoto, Masanobu Uchiyama, Mikiko Sodeoka

NATURE COMMUNICATIONS   8   14875;1 - 10   2017.4

Indium-Catalyzed Formal N-Arylation and N-Alkylation of Pyrroles with Amines Reviewed

Kyohei Yonekura, Kenji Oki, Teruhisa Tsuchimoto

ADVANCED SYNTHESIS & CATALYSIS   358 ( 18 )   2895 - 2902   2016.9

Easy Access to a Library of Alkylindoles: Reductive Alkylation of Indoles with Carbonyl Compounds and Hydrosilanes under Indium Catalysis Reviewed

Shota Nomiyama, Takehiro Hondo, Teruhisa Tsuchimoto

ADVANCED SYNTHESIS & CATALYSIS   358 ( 7 )   1136 - 1149   2016.3

Carboxylative cyclization of propargylic amines with CO2 catalyzed by dendritic N-heterocyclic carbene-gold(I) complexes Reviewed

Ken-ichi Fujita, Kensuke Inoue, Junichi Sato, Teruhisa Tsuchimoto, Hiroyuki Yasuda

TETRAHEDRON   72 ( 9 )   1205 - 1212   2016.3

Alkynylboranes: A Practical Approach by Zinc-Catalyzed Dehydrogenative Coupling of Terminal Alkynes with 1,8-Naphthalenediaminatoborane Reviewed

Teruhisa Tsuchimoto, Hirokazu Utsugi, Tetsuya Sugiura, Shin Horio

ADVANCED SYNTHESIS & CATALYSIS   357 ( 1 )   77 - 82   2015.1

Metal-Free Regioselective beta-Alkylation of Pyrroles with Carbonyl Compounds and Hydrosilanes: Use of a Bronsted Acid as a Catalyst Reviewed

Shota Nomiyama, Teruhisa Tsuchimoto

ADVANCED SYNTHESIS & CATALYSIS   356 ( 18 )   3881 - 3891   2014.12

RE12 derivatives displaying Vaccinia H1-related phosphatase (VHR) inhibition in the presence of detergent and their anti-proliferative activity against HeLa cells Reviewed

Frederic Thuaud, Shuntaro Kojima, Go Hirai, Kana Oonuma, Ayako Tsuchiya, Takako Uchida, Teruhisa Tsuchimoto, Mikiko Sodeoka

BIOORGANIC & MEDICINAL CHEMISTRY   22 ( 9 )   2771 - 2782   2014.5

Aqueous media carboxylative cyclization of propargylic amines with CO2 catalyzed by amphiphilic dendritic N-heterocyclic carbene-gold(I) complexes Reviewed

Ken-ichi Fujita, Junichi Sato, Kensuke Inoue, Teruhisa Tsuchimoto, Hiroyuki Yasuda

TETRAHEDRON LETTERS   55 ( 19 )   3013 - 3016   2014.5

Indium-catalyzed heteroaryl–heteroaryl bond formation through nucleophilic aromatic substitution: preparation of 2-methyl-3-(thien-2-yl)-1H-indole Reviewed

Nagase, Y, Tsuchimoto, T

Org. Synth.   91   273 - 282   2014.3

Zinc-Catalyzed Direct Cyanation of Indoles and Pyrroles: Nitromethane as a Source of a Cyano Group Reviewed

Yuta Nagase, Tetsuya Sugiyama, Shota Nomiyama, Kyohei Yonekura, Teruhisa Tsuchimoto

ADVANCED SYNTHESIS & CATALYSIS   356 ( 2-3 )   347 - 352   2014.2

Indium-catalyzed Annulation of Indoles with Ethyl (2-Ethynylaryl)methyl Carbonates: Synthesis and Photo luminescent Properties of Aryl- and Heteroaryl[b]carbazoles Reviewed

Yuta Nagase, Takuhiro Miyamura, Kensuke Inoue, Teruhisa Tsuchimoto

CHEMISTRY LETTERS   42 ( 10 )   1170 - 1172   2013.10

Indium-catalyzed annulation of 3-aryl- and 3-heteroarylindoles with propargyl ethers: synthesis and photoluminescent properties of aryl- and heteroaryl[c]carbazoles Reviewed

Yuta Nagase, Hiroyuki Shirai, Masayoshi Kaneko, Eiji Shirakawa, Teruhisa Tsuchimoto

ORGANIC & BIOMOLECULAR CHEMISTRY   11 ( 9 )   1456 - 1459   2013

Homogeneous Dihydroxylation of Olefins Catalyzed by OsO42- Immobilized on a Dendritic Backbone with a Tertiary Nitrogen at Its Core Position Reviewed

Ken-ichi Fujita, Kensuke Inoue, Teruhisa Tsuchimoto, Hiroyuki Yasuda

CHEMICAL & PHARMACEUTICAL BULLETIN   60 ( 12 )   1594 - 1598   2012.12

Dehydrogenative Silylation of Terminal Alkynes with Hydrosilanes under Zinc-Pyridine Catalysis Reviewed

Teruhisa Tsuchimoto, Masakazu Fujii, Yoshihiko Iketani, Masaru Sekine

ADVANCED SYNTHESIS & CATALYSIS   354 ( 16 )   2959 - 2964   2012.11

Zinc-Catalyzed Dehydrogenative N-Silylation of Indoles with Hydrosilanes Reviewed

Teruhisa Tsuchimoto, Yoshihiko Iketani, Masaru Sekine

CHEMISTRY-A EUROPEAN JOURNAL   18 ( 31 )   9500 - 9504   2012.7

Development of New Catalytic Reactions Based on Activation of Hydrocarbon Functional Groups by Lewis Acids

Teruhisa Tsuchimoto

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   69 ( 8 )   889 - 903   2011.8

Catalytic Asymmetric alpha-Chlorination of 3-Acyloxazolidin-2-one with a Trinary Catalytic System

Yoshitaka Hamashima, Tatsuya Nagi, Ryo Shimizu, Teruhisa Tsuchimoto, Mikiko Sodeoka

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY   ( 20-21 )   3675 - 3678   2011.7

Magnetically recoverable osmium catalysts for dihydroxylation of olefins

Ken-ichi Fujita, Satoshi Umeki, Manabu Yamazaki, Taku Ainoya, Teruhisa Tsuchimoto, Hiroyuki Yasuda

TETRAHEDRON LETTERS   52 ( 24 )   3137 - 3140   2011.6

Selective Synthesis of beta-Alkylpyrroles

Teruhisa Tsuchimoto

CHEMISTRY-A EUROPEAN JOURNAL   17 ( 15 )   4064 - 4075   2011.4

Reductive Alkylation of Indoles with Alkynes and Hydrosilanes under Indium Catalysis

Teruhisa Tsuchimoto, Mitsutaka Kanbara

ORGANIC LETTERS   13 ( 5 )   912 - 915   2011.3

Microwave-assisted organic functionalization of silica surfaces: Effect of selectively heating silylating agents

Norihisa Fukaya, Hiroshi Yamashita, Hisato Haga, Teruhisa Tsuchimoto, Syun-ya Onozawa, Toshiyasu Sakakura, Hiroyuki Yasuda

JOURNAL OF ORGANOMETALLIC CHEMISTRY   696 ( 4 )   825 - 828   2011.2

Indium-Catalyzed Heteroaryl-Heteroaryl Bond Formation through Nucleophilic Aromatic Substitution

Teruhisa Tsuchimoto, Mami Iwabuchi, Yuta Nagase, Kenji Oki, Hiroshi Takahashi

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   50 ( 6 )   1375 - 1379   2011

Organic functionalization of the surface of silica with arylsilanes. A new method for synthesizing organic-inorganic hybrid materials

Norihisa Fukaya, Hisato Haga, Teruhisa Tsuchimoto, Syun-ya Onozawa, Toshiyasu Sakakura, Hiroyuki Yasuda

JOURNAL OF ORGANOMETALLIC CHEMISTRY   695 ( 23 )   2540 - 2542   2010.11

A recyclable dendritic osmium catalyst for homogeneous dihydroxylation of olefins

Ken-ichi Fujita, Manabu Yamazaki, Taku Ainoya, Teruhisa Tsuchimoto, Hiroyuki Yasuda

TETRAHEDRON   66 ( 44 )   8536 - 8543   2010.10

Development of innovative one-step synthesis of .beta.-alkylpyrroles

Meiji Daigaku Kagaku Gijyutsu Kenkyusho Nenpo   50   68-69   2010.3

Homogeneous dihydroxylation of olefins catalyzed by a recyclable OsO42- core dendrimer

Ken-ichi Fujita, Taku Ainoya, Teruhisa Tsuchimoto, Hiroyuki Yasuda

TETRAHEDRON LETTERS   51 ( 5 )   808 - 810   2010.2

Exclusive Synthesis of beta-Alkylpyrroles under Indium Catalysis: Carbonyl Compounds as Sources of Alkyl Groups

Teruhisa Tsuchimoto, Motohiro Igarashi, Kazuki Aoki

CHEMISTRY-A EUROPEAN JOURNAL   16 ( 30 )   8975 - 8979   2010

Indium-Catalyzed Reductive Alkylation of Pyrroles with Alkynes and Hydrosilanes: Selective Synthesis of beta-Alkylpyrroles

Teruhisa Tsuchimoto, Tatsuya Wagatsuma, Kazuki Aoki, Jun Shimotori

ORGANIC LETTERS   11 ( 10 )   2129 - 2132   2009.5

Synthesis of Methanes Having Four Different Carbon Substituents Utilizing Indium-Catalyzed Cleavage of Carbon-Pyrrolyl Bonds

Teruhisa Tsuchimoto, Taku Ainoya, Kazuki Aoki, Tatsuya Wagatsuma, Eiji Shirakawa

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY   ( 15 )   2437 - 2440   2009.5

Indium-Catalyzed Annulation of 2-Aryl- and 2-Heteroarylindoles with Propargyl Ethers: Concise Synthesis and Photophysical Properties of Diverse Aryl- and Heteroaryl-Annulated[a]carbazoles

Teruhisa Tsuchimoto, Hiromichi Matsubayashi, Masayoshi Kaneko, Yuta Nagase, Takuhiro Miyamura, Eiji Shirakawa

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   130 ( 47 )   15823 - 15835   2008.11

Lewis acid catalyzed addition of pyrazoles to alkynes: Selective synthesis of double and single addition products

Teruhisa Tsuchimoto, Kazuki Aoki, Tatsuya Wagatsuma, Yuichi Suzuki

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY   ( 23 )   4035 - 4040   2008.8

Direct coupling of N-H bond and H-C bond

Organometallic News   ( 2 )   82   2008.5

Stereochemistry in Lewis acid-catalyzed silylation of alcohols, silanols, and methoxysilanes with optically active methyl(1-naphthyl)phenylsilane

Satoshi Shinke, Teruhisa Tsuchimoto, Yusuke Kawakami

Silicon Chemistry   3 ( 5 )   243 - 249   2007.4

Ruthenium-catalyzed addition of terminal alkynes to alkynylstannanes with migration of the stannyl group

Eiji Shirakawa, Kouji Nakayama, Ryotaro Morita, Teruhisa Tsuchimoto, Yusuke Kawakami, Toshiaki Matsubara

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   79 ( 12 )   1963 - 1976   2006.12

Studies on carbon-carbon bond forming reactions utilizing activation of unsaturated hydrocarbons and heteroaromatic compounds by metal sulfonate catalysts

Teruhisa Tsuchimoto

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   64 ( 7 )   752 - 765   2006.7

Nickel-catalyzed addition of organoboronates to 1,2-dienes and the corresponding three-component reaction with an alkyne

Go Takahashi, Eiji Shirakawa, Teruhisa Tsuchimoto, Yusuke Kawakami

ADVANCED SYNTHESIS & CATALYSIS   348 ( 7-8 )   837 - 840   2006.5

A simple catalyst system for the palladium-catalyzed coupling of aryl halides with terminal alkynes

E Shirakawa, T Kitabata, H Otsuka, T Tsuchimoto

TETRAHEDRON   61 ( 41 )   9878 - 9885   2005.10

Indium-catalysed synthesis of aryl- and heteroaryl-annulated carbazoles: systematic inveatigation of their emission properties

IUPAC OMCO-13 Abstracts Geneva   2005.7

Synthesis of multisubstituted 1,3-butadienes using the ruthenium-catalysed double addition of trimethylsilyldiazomethane to alkynylboronates

R Morita, E Shirakawa, T Tsuchimoto, Y Kawakami

ORGANIC & BIOMOLECULAR CHEMISTRY   3 ( 7 )   1263 - 1268   2005

Easy access to aryl- and heteroaryl-annulated[a]carbazoles by the indium-catalyzed reaction of 2-arylindoles with propargyl ethers

T Tsuchimoto, H Matsubayashi, M Kaneko, E Shirakawa, Y Kawakami

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   44 ( 9 )   1336 - 1340   2005

Alkynes as activators in the nickel-catalysed addition of organoboronates to aldehydes

G Takahashi, E Shirakawa, T Tsuchimoto, Y Kawakami

CHEMICAL COMMUNICATIONS   ( 11 )   1459 - 1461   2005

'Synthetic strategy for functionalized polyacene atructure using nickel-catalyzed alkynylstannylation of 1,2-dienes'

Trans. MRS-J.   29   pp93-96   2004.11

Nickel-catalyzed acylstannylation and alkynylstannylation of 1,2-dienes

Y Nakao, E Shirakawa, T Tsuchimoto, T Hiyama

JOURNAL OF ORGANOMETALLIC CHEMISTRY   689 ( 23 )   3701 - 3721   2004.11

Ruthenium-catalyzed hydrogenation of alkynylstannanes with migration of the stannyl group

E Shirakawa, R Morita, T Tsuchimoto, Y Kawakami

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   126 ( 42 )   13614 - 13615   2004.10

Nickel-catalyzed tandem carbostannylation of alkynes and 1,2-dienes with alkynylstannanes

E Shirakawa, Y Yamamoto, Y Nakao, S Oda, T Tsuchimoto, T Hiyama

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   43 ( 26 )   3448 - 3451   2004

Zirconium triflate catalyzed direct coupling reaction of lactams with heterocyclic arenes under atmospheric oxygen

T Tsuchimoto, Y Ozawa, R Negoro, E Shirakawa, Y Kawakami

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   43 ( 32 )   4231 - 4233   2004

A p-phosphinophenolate ligand for the palladium-catalysed arylation of alkenes

E Shirakawa, K Ishii, T Tsuchimoto

CHEMICAL COMMUNICATIONS   ( 23 )   2752 - 2753   2004

Indium triflate-catalysed double addition of heterocyclic arenes to alkynes

T Tsuchimoto, K Hatanaka, E Shirakawa, Y Kawakami

CHEMICAL COMMUNICATIONS   ( 19 )   2454 - 2455   2003.10

Palladium-catalysed dimerization of vinylarenes using indium triflate as an effective co-catalyst

T Tsuchimoto, S Kamiyama, R Negoro, E Shirakawa, Y Kawakami

CHEMICAL COMMUNICATIONS   ( 7 )   852 - 853   2003

'Synthesis of polycyclic compounds utilizing the nickel-catalysed alkynylstannylation of 1,2-dienes'

'RSC Publishing, Chem. Commun.'   pp1962-1963   2002.8

Metal triflate-catalyzed addition of arenes to alkynes

The 2nd JAIST-POSTEC joint symposium Abstracts   p30   2002.3

Nickel-catalysed addition of organoboronates to 1,3-dienes

E Shirakawa, G Takahashi, T Tsuchimoto, Y Kawakami

CHEMICAL COMMUNICATIONS   ( 19 )   2210 - 2211   2002

光学活性アミンを不斉源とする華麗な触媒的不斉合成反応

土本晃久

日本化学会   54 ( 12 )   1392 - 1392   2001.12

Nickel-catalysed hydroarylation of alkynes using arylboron compounds: selective synthesis of multisubstituted arylalkenes and aryldienes

E Shirakawa, G Takahashi, T Tsuchimoto, Y Kawakami

CHEMICAL COMMUNICATIONS   ( 24 )   2688 - 2689   2001.12

Dimerization of alkenes catalyzes by a palladium-metal triflate system

PostOMCO-11 Abstacts   p168   2001.7

Transition metal-catalysed acylation of α,β-unsaturated carbonyl compounds with acylstannanes

Eiji Shirakawa, Youko Yamamoto, Yoshiaki Nakao, Teruhisa Tsuchimoto, Tamejiro Hiyama

Chemical Communications   1 ( 19 )   1926 - 1927   2001

Bronsted acid-catalyzed hydration of alkynes: A convenient route to diverse carbonyl compounds

T Tsuchimoto, T Joya, E Shirakawa, Y Kawakami

SYNLETT   ( 12 )   1777 - 1778   2000.12

Friedel-Crafts alkenylation of arenes using alkynes catalysed by metal trifluoromethanesulfonates

T Tsuchimoto, T Maeda, E Shirakawa, Y Kawakami

CHEMICAL COMMUNICATIONS   ( 17 )   1573 - 1574   2000

Friedel-Crafts alkenylation of arenes using alkynes catalysed by metal trifluoromethanesulfonates

T Tsuchimoto, T Maeda, E Shirakawa, Y Kawakami

CHEMICAL COMMUNICATIONS   ( 17 )   1573 - 1574   2000

Synthetic applications of ortho esters

P Wipf, T Tsuchimoto, H Takahashi

PURE AND APPLIED CHEMISTRY   71 ( 3 )   415 - 421   1999.3

Superacid-catalyzed reductive Friedel-Crafts reaction of arenes using arenecarbaldehyde acetals

S Fukuzawa, T Tsuchimoto, T Hiyama

JOURNAL OF ORGANIC CHEMISTRY   62 ( 1 )   151 - 156   1997.1

Scandium(III) Triflate-Catalyzed Friedel-Crafts Alkylation Reactions

Teruhisa Tsuchimoto, Kazuo Tobita, Tamejiro Hiyama, Shin-Ichi Fukuzawa

Journal of Organic Chemistry   62 ( 20 )   6997 - 7005   1997

Scandium(III) trifluoromethanesulfonate-catalysed reductive Friedel-crafts benzylation of aromatic compounds using arenecarbaldehydes and propane-1,3-diol

T Tsuchimoto, T Hiyama, S Fukuzawa

CHEMICAL COMMUNICATIONS   ( 20 )   2345 - 2346   1996.10

Samarium(II) triflate as a new reagent for the Grignard-type carbonyl addition reaction

'ACS Publications, J. Org. Chem.'   61   pp5400-5405   1996.7

Scandium (III) triflate catalyzed Friedel-Crafts alkylation with benzyl and allyl alcohols

T Tsuchimoto, K Tobita, T Hiyama, SI Fukuzawa

SYNLETT   ( 6 )   557 - &   1996.6

Alkylation-annulation of halo esters with organometallic reagent/SmI2 couple leading to cycloalkanols: A facile cyclopropanol synthesis from a 3-halo ester

S Fukuzawa, H Furuya, T Tsuchimoto

TETRAHEDRON   52 ( 6 )   1953 - 1960   1996.2

DIRECT SYNTHESIS OF CHIRAL ACETALS FROM CARBONYL-COMPOUNDS AND CHIRAL DIOLS - SEQUENTIAL ONE-POT ASYMMETRIC SILYLCYANATION REACTION CATALYZED BY SCANDIUM(III) TRIFLATE

S FUKUZAWA, T TSUCHIMOTO, T HOTAKA, T HIYAMA

SYNLETT   ( 10 )   1077 - &   1995.10

A FACILE CONVERSION OF SUBSTITUTED CYCLOBUTANONES TO CYCLOPENTANONES BY CH2I2/SMI2 SYSTEM

S FUKUZAWA, T TSUCHIMOTO

TETRAHEDRON LETTERS   36 ( 33 )   5937 - 5938   1995.8

A facile one-pot synthesis of chiral acetals and subsequent C-C bond forming reactions catalyzed by Ln(OTf)3

IUPAC OMCO-8 Abstracts Santa Barbara   p205   1995.8

YTTERBIUM TRIFLUOROMETHANESULFONATE MEDIATED CROSS-ALDOL REACTION BETWEEN KETONES AND ALDEHYDES

S FUKUZAWA, T TSUCHIMOTO, T KANAI

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   67 ( 8 )   2227 - 2232   1994.8

Preparation of samarium(II) triflate and it mediated Grignard-type reaction. In situ formation and reaction of new organosamarium reagents

FUKUZAWA Shin-ichi, TSUCHIMOTO Teruhisa, KANAI Takeshi

Chem.Lett.   1994 ( 11 )   pp1981-1984 - 1984   1994.8

SAMARIUM(II) DIIODIDE INDUCED INTRAMOLECULAR COUPLING REACTION OF HALOCETALS LEADING TO THE SYNTHESIS OF GAMMA-LACTONES

S FUKUZAWA, T TSUCHIMOTO

SYNLETT   ( 10 )   803 - 804   1993.10

Samarium(II) diiodide induced intramolecular coupling reaction of haloacetals leading to synthesis of γ-lactones

IUPAC OMCO-7 Abstracts   p107   1993.9

芳香族求核置換反応を利用するビアリールおよびトリアリール類の革新的合成法の開発

2007.4 - 2009.3

若手研究 (B) 

π 電子系ナノロッドの創成と単一分子発光ダイオードへの展開

2004.4 - 2008.3

基盤研究 (B) 

縮合多環式芳香族化合物の簡便合成法の確立と新規有機 EL 発光材料開発への応用

2004.4 - 2006.3

若手研究 (B) 

パラジウム−金属トリフラート複合系触媒による新しい炭素−炭素結合形成反応の開発

2001.4 - 2003.3

奨励研究